The demand for energy storage technologies is rapidly increasing due to the development of grid-scale energy storage applications. Sodium-ion storage devices have been considered as potential candidates for large-scale energy storage systems owing to the natural abundance and low price of sodium resources. As a cost-effective and versatile method, electrospinning has been used to fabricate designed one-dimensional architectures with targeted components for advanced energy storage systems. Benefiting from the large surface area, continuous one-dimensional charge transportation channels and short distant for ionic transport, electrospun materials are helpful to improve the electrochemical sodium storage performance of the devices.